Overview In this chapter we study the structures and properties of orthogonal and pseudoorthogonal sequences. Firstly, we examine several types of pseudo-orthogonal (PN) and Quasi-Orthogonal (QO) sequences, and present their cross-correlation properties under synchronous and asynchronous conditions. Secondly, we survey basic methods of constructing orthogonal code sets. Orthogonal binary (Hadamard) codes may exist for lengths 1, 2 and 4k (for k = 1, 2, 3, ...). Methods for generating all lengths